بهینه‎سازی و بررسی حذف آفت‎کش دلتامترین از محیط‌های آبی توسط کامپوزیت کربن فعال مغناطیسی AC/Fe3O4 با استفاده از روش سطح پاسخ RSM-BBD

نوع مقاله : مقاله پژوهشی

نویسندگان

1 کارشناس ارشد مهندسی پلیمر، دانشکده شیمی، دانشگاه تبریز، تبریز، ایران.

2 دانشیار آزمایشگاه پژوهشی پلیمر، گروه شیمی آلی و بیوشیمی، دانشکده شیمی، دانشگاه تبریز، تبریز، ایران.

چکیده

آلودگی آب‌های سطحی توسط آفت‎کش‎ها یکی از مهم‎ترین آلودگی‌های محیط‎زیست است. در این مطالعه کامپوزیت مغناطیسی کربن فعال/ نانوذرات آهن (AC/Fe3O4) سنتز و در جذب سم دلتامترین از محلول آبی مورد استفاده قرارگرفت. آنالیزهایFT-IR ، SEM، XRD و VSM مطالعه خصوصیات جاذب مورد استفاده قرارگرفت. نتایج این آنالیزها نشان‎داد که جاذب موردنظر با موفقیت سنتز شده است. با استفاده از روش سطح پاسخ (RSM)، طراحی آزمایش به‎روش باکس-بنکن (BBD) رفتار جاذب در جذب آفت‌کش دلتامترین و هم‎چنین به‎دست آوردن شرایط بهینه جذب مورد مطالعه قرارگرفت. نتایج نشان‎داد که بیشینه ظرفیت جذب جاذب موردنظر در شرایط مورد بررسی برای آفت‌کش دلتامترین برابر با mg/g 170/99 میلی‏گرم بر گرم است. هم‎چنین بهترین مدل برای بیان فرآیند جذب سم دلتامترین توسط جاذب مورد بررسی مدل ایزترمی سیپ است، که از معادله سینتیک شبه درجه دوم پیروی می‏کند. بنابراین تعاملات بین جاذب و دارو به‏صورت واکنش‏های شیمیایی است. ازسوی دیگر نتایج ترمودینامیکی نشان‎داد فرآیند به‌صورت گرمازا و با مقدار آنالپی برابرKJ/mol  79/54 است. نتایج این مطالعه نشان‎داد که کامپوزیت مغناطیسی AC/Fe3O4 توانایی استفاده‎شدن تا 10 مرحله فرآیند جذب و واجذب سم دلتامترین با درصد جذب بیشتر از 95% را دارا است.

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