A Review on Boron Removal from Seawater Using Reverse Osmosis Technology

Document Type : Review Paper

Authors

1 Assistant Professor, Department of Geology, Estahban branch, Islamic Azad University, Estahban, Iran.

2 Associate Professor, Department of Chemistry, Darab branch, Islamic Azad University (and Department of Applied Researches, Chemical, Petroleum & Polymer Engineering Research Center, Shiraz branch, Islamic Azad University, Shiraz), Iran.

3 Assistant Professor, Department of Polymer Engineering, Shiraz branch, Islamic Azad University, Shiraz, Iran.

Abstract

It is predicted that by 2050, more than 48% of the world's population will face water shortages. Desalination of seawater as the best way to supply fresh water has been on the rise for the past three decades. Membrane desalination methods, especially reverse osmosis, have become more popular than other methods due to their lower energy consumption. Despite the success of this method in removing seawater salts, contaminants such as boron are still found in the produced water due to the presence of boron as boric acid in seawater, which due to its small molecular size, leaks into the produced water through membranes. The average concentration of boron in seawater is 4.6 mg/l, which comes from various natural sources such as volcanic activity as well as anthropogenic sources. High levels of boron are harmful to human health and agricultural products. Factors such as pH, temperature and ionic strength of feed water have a great impact on boron removal in membrane processes. By examining credible sources, while pointing to the importance of boron and its removal methods, this validity review article addresses the challenges of boron removal by reverse osmosis as the most common seawater desalination technology.

Keywords


 
پسندیده‌پور، ف.، غلامی، ف.، و اسدی، آ.، (1400)، "مروری بر عملکرد غشاهای نانوفیلتراسیون اصلاح شده با نانومواد معدنی، کربنی و ترکیبی از آن‌ها"، علوم و مهندسی آب و فاضلاب،  8(1)،  https://doi.org/10.22112/jwwse.2022.316060.1297
سامی‌حصار، ب.، ضرغامی، م.، یگانی، ر.، و صباحی، م.، (1398)، "طراحی سیستم آب‌شیرین‌کن خورشیدی به‌روش اسمز معکوس- فتوولتائیک (مطالعه موردی: آب لب‌شور روستای سربند اردبیل)"، علوم و مهندسی آب و فاضلاب، 4(2)، 37-46.
Bao, X., Long, W., Liu, H., and She, Q., (2021), “Boron and salt ion transport in electrically assisted reverse osmosis”, Journal of Membrane Science, 637, 119639, https://doi.org/10.1016/j.memsci.2021.119639.
Bhagyaraj, S., Al-Ghouti, M.A., Kasak, P., and Krupa, I., (2021), “An updated review on boron removal from water through adsorption processes”, Emergent Materials, 4, 1167-1186.
Boccaletti, G., Grobbel, M., and Stuchtey, M.R., (2010), “The business opportunity in water conservation”, McKinsey Quarterly, December 1, 67-75.
Cengeloglu, Y., Arslan, G., Tor, A., Kocak, I., and ve Dursun, N., (2008), “Removal of boron from water by using reverse osmosis”, Separation and Purification Technology, 64(2), 141-146.
Curto, D., Franzitta, V., and Guercio, A., (2021), “A review of the water desalination technologies”, Applied Sciences, 11(2), 670.
Dydo, P., Turek, M., Ciba, J., Trojanowska, J., and Kluczka, J., (2005), “Boron removal from landfill leachate by means of nanofiltration and reverse osmosis”, Desalination, 185(1-3), 131-137.
Eke, J., Yusuf, A., Giwab, A., and Sodiq, A., (2020), “The global status of desalination: An assessment of current desalination technologies, plants and capacity”, Desalination, 495, 114633,  https://doi.org/10.1016/j.desal.2020.114633.
EPA, (2008), Drinking water health advisory for boron, Health and Ecological Criteria Division Office of Science and Technology Office of Water, Document Number: 822-R-08-013, Washington, D.C., USA.
Farhat, A., Ahmad, F., Hilal, N., and Arafat, H.A., (2013), “Boron removal in new generation reverse osmosis (RO) membranes using two-pass RO without pH adjustment”, Desalination, 310, 50-59, https://doi.org/10.1016/j.desal.2012.10.003.
Geffen, N., Semiat, R., Eisen, M., and Balazs, Y.S., (2006), “Boron removal from water by complexation to polyol compounds”, Journal of Membrane Science, 286(1-2), 45-51.
Hilal, N., Kim, G., and Somerfield, C., (2011), “Boron removal from saline water: A comprehensive review”, Desalination, 273(1), 23-35, https://doi.org/10.1016/j.desal.2010.05.012.
Hung, P.V.X., Cho, S-H., and Moon, S-H., (2009), “Prediction of boron transport through seawater reverse osmosis membranes using solution-diffusion model”, Desalination, 247(1-3), 33-44.
Hunt, C.D., and Benjamin, C., (2003), “Boron”, In: Encyclopedia of Food Sciences and Nutrition, Academic Press, Oxford, 566-574.
Inamuddin, Ahamed, M.I., Lichtfouse, E., and Asiri, A.M., (2021), Green adsorbents to remove metals, dyes and boron from polluted water, Environmental Chemistry for a Sustainable World 49, Springer Nature Switzerland AG, 462 p.
Jones, E., Qadir, M., van Vliet, M.T.H., Smakhtin, V., Kang, S.M., (2019), “The state of desalination and brine production: A global outlook”, Science of The Total Environment, 657, 1343-1356, https://doi.org/10.1016/j.scitotenv.2018.12.076.
Kabay, N., Bryjak, M., and Hilal, N., (2015), Boron separation processes, Elsevier; 1st Edition, ‎ 412 p.
Kürklüa, S., Velioğlua, S., Ahunbaya, M.G., Tantekin-Ersolmaza, S.B., and Krantzb, W.B., (2017), “A novel energy-efficient concurrent desalination and boron removal (CDBR) process”, Desalination, 423, 79-94, https://doi.org/10.1016/j.desal.2017.09.005.
Lim, Y.J., Goh, K., Kurihara, M., and Wang, R., (2021), “Seawater desalination by reverse osmosis: Current development and future challenges in membrane fabrication, A review”, Journal of Membrane Science, 629, 119292, https://doi.org/10.1016/j.memsci.2021.119292.
Lin, J.Y., Mahasti, N.N.N., and Huang, Y.H., (2020), “Recent advances in adsorption and coagulation for boron removal from wastewater: a comprehensive review”, Journal of Hazardous Materials, 407, 124401, https://doi.org/10.1016/j.jhazmat.2020.124401.
Nable, R.O., Ba˜nuelos, G.S., and Paull, J.G., (1997), “Boron toxicity”, Plant and Soil, 193(1), 181-198.
Nadav, N., Koutsakos, E., (2013), “Innovative design of the UF and SWRO Limassol desalination plant in Cyprus”, Desalination and Water Treatment, 51(1-3), 95-100.
Najid, N., Kouzbour, S., Ruiz-García, A., Fellaou, S., Gourich, B., and Stiriba, Y., (2021), “Comparison analysis of different technologies for the removal of boron from seawater: A review”, Journal of Environmental Chemical Engineering, 9(2), 1-20, https://doi.org/10.1016/j.jece.2021.105133.
Park, B., Lee, J., Kim, M., Sun Won, Y., Lim, J.K., and Kim, S. (2015) “Enhanced boron removal using polyol compounds in seawater reverse osmosis processes”, Desalination and Water Treatment, 57(17), 7910-7917, https://doi.org/10.1080/19443994.2015.1038596.
Rahmawati, K., (2011), “Boron removal in seawater reverse osmosis system”, M.Sc. Thesis, King Abdullah University of Science and Technology, Thuwal, Kingdom of Saudi Arabia.
Redondo, J., Busch, M., and De Witte, J.P., (2003), “Boron removal from seawater using FILMTECTM high rejection SWRO membranes”, Desalination, 156(1-3), 229-238.
Regis, A.O., Vanneste, J., Acker, S., Martínez, G., Ticona, J., García, V., Alejo, F.D., Zea, J., Krahenbuhl, R., Vanzin, G., and Sharp, J.O., (2022), “Pressure-driven membrane processes for boron and arsenic removal: pH and synergistic effects”, Desalination, 522, 115441, https://doi.org/10.1016/j.desal.2021.115441.
Ruiz-García, A., and Nuez, I., (2021), “Performance evaluation and boron rejection in a SWRO system under variable operating conditions”, Computers and Chemical Engineering, 153, 07441, https://doi.org/10.1016/j.compchemeng.2021.107441
Tang, Y.P., Luo, L., Thong, Z., and Chung, T.S., (2017), “Recent advances in membrane materials and technologies for boron removal”, Journal of Membrane Science, 541, 434-446, https://doi.org/10.1016/j.memsci.2017.07.015.
Tappe, A., (2020), “Investors can now trade water futures-CNN”, Accessed on 12 December 2020, https://edition.cnn.com/2020/12/07/investing/water-futures-trading/index.html.
Tu, K.L., Nghiem, L.D., and Chivas, A.R., (2010), “Boron removal by reverse osmosis membranes in seawater desalination applications”, Separation and Purification Technology, 75(2), 87-101.
WHO and IPCS, (‎1998),‎ Boron, World Health Organization, Geneva, https://apps.who.int/iris/handle/10665/42046
WHO, (2003) Boron in drinking-water, Background document for development of WHO guidelines for drinking-water quality, WHO/SDE/WSH/03.04/54, Geneva.
Xu, J., Xu, J., Gao, X., Chen, G., Zou, L., and Gao, C. (2010) “High performance boron removal from seawater by two-pass SWRO system with different membranes”, Water Science and Technology: Water Supply, 10(3), 327-336.
Zetland, D. (2021) “The role of prices in managing water scarcity”, Water Security, 12, 100081, scarcity”, Water Security, 12, 100081, https://doi.org/10.1016/j.wasec.2020.100081.